Sodium naphthalene sulfonate formaldehyde as raw materials

Acrylic acid, acrylamide, and sodium naphthalene sulfonate formaldehyde as raw materials, ammonium persulfate as an initiator, synthesized by free radical solution copolymerization of a polycarboxylate superplasticizer, as demonstrated by a variety of detection methods for the synthesis of substance is a terpolymer, and its performance was tested. The effects of reaction temperature, the amount of initiator and pH on polymer yield and structure. With a relatively simple synthesis of a high yield and excellent performance sodium naphthalene sulfonate formaldehyde. Also known as dispersants or water reducing agent, plasticizer, is a class of the most common and important concrete admixture. Less than 5% water rate less than 10% of the reducing agent called ordinary water, water reduction rate of more than 10% of the water reducer called sodium naphthalene sulfonate formaldehyde. Superplasticizer as the fifth component of modern concrete, which is widely applied, has become an important means of high-performance concrete.

Polyethylene glycol methyl ether (MPEG), methacrylic acid (MAA), allyl sulfonate (SAS) and ammonium persulfate (APS) as a raw material monomer such as synthesis of a sodium naphthalene sulfonate formaldehyde , the effect of factors that lead to agents, chain transfer agent, monomer fluidity of cement paste, and analyzes the relationship between different superplasticizer concentration and surface tension; studies show that when the amount of the monomer initiator quality 5 %, the chain transfer agent is 0.3%, SAS is 15%, MAA / MPEG molar ratio of 8:00, water reducing agent for cement better dispersion and plasticity of different cement has good adaptability. In recent years, high performance concrete, sodium naphthalene sulfonate formaldehyde attracted widespread attention. And lignin sulfonate superplasticizer and naphthalene superplasticizer compared superplasticizer with high water reduction, high slump resistance, cement adaptability advantages. Polylactic acid is a polymer having a comb structure of surfactant molecules can be designed strong structure, can control the degree of sodium naphthalene sulfonate formaldehyde of the main chain.

By measuring doped sodium naphthalene sulfonate formaldehyde cement paste setting time, chemical shrinkage, the initial heat of hydration, compressive strength, while taking advantage of XRD analysis, the effect of cement hydration under water reducing agent were studied. Effects of sodium naphthalene sulfonate formaldehyde. The results showed that: Polycarboxylate has a strong retarding effect while having good dispersion, effectively inhibit the initial hydration, without affecting the post-hydration.

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